Fadzlina Abdullah1*, Nur Aainaa Syahirah Ramli1, Fumiya Niikura2 And Zulina Abd. Maurad1
1Advanced Oleochemical Technology Division, Malaysian Palm Oil Board, 6, Persiaran Institusi, Bandar Baru Bangi, 43 000 Kajang, Selangor, Malaysia
2Functional Material Science Research Laboratory, Lion Corporation, 2-1 Hirai 7-Chome, Edogawa-ku, Tokyo 132-0035, Japan. *Corresponding author : email@example.com
Received 8th May 2021 ; accepted 18nd October 2021
Available online 20th December 2021
ABSTRACT. Palm-based methyl ester sulphonate (MES) is an anionic surfactant derived from renewable resources by sulphonation of palm methyl ester with sulphur trioxide and can be used as an alternative to the conventional linear alkylbenzenesulphonate. MES has been shown to possess favourable environmental characteristics, water hardness tolerance, with excellent detergency and foaming properties that are useful in detergent industry. Due to its great potential as surfactant in consumer products, it is crucial to determine its physical properties to protect consumer safety and the ecosystem. Physical properties are important aspects of a chemical because they play a significant role in determining its possible applications. Therefore, this study aims to determine the physical properties of various homologues of palm-based MES, such as C12-, C14-, C16-, and C16:18- MES. The selected physical properties included physical appearance (form, colour, and odour), functional groups via Fourier-transform infrared (FTIR) spectroscopy, density, melting point, and flammability. The sulphonation process to produce MES was confirmed through sulphonationcation interactions from the FTIR spectra. A better understanding of the properties and applicability of MES in different areas can be assessed through the study of their physical properties. Information on these properties is important, whereby the specifications of palm-based MES can be used to find the best formulation for its applications and support the regulatory requirements of importing countries, e.g., Registration, Evaluation, Authorisation and Restriction of Chemicals (REACh), to facilitate market penetration.
KEYWORDS.Anionic surfactant; Palm-based; methyl ester sulphonate; Detergent; properties.
- Agency, E. C. (2012). Practical Guide 3: How to report robust study summaries. https://echa.europa.eu/documents/10162/13643/pg_report_robust_study_summaries_en.pdf, accessed on 22 January 2019.
- American Oil Chemists’ Society and Mehlenbacher, V. C. (2004).Official Methods and Recommended Practices of the AOCS, American Oil Chemists’ Society.https://www.aocs.org/attain-lab-services/methods/methods/search, accessed on 3 February 2019.
- Ariba, H; Wang, Y; Devouge-Boyer, C; Stateva, R P and Leveneur, S (2020). Physicochemical properties for the reaction systems: Levulinic acid, its esters, and γ-valerolactone. Journal of Chemical & Engineering Data, 65: 3008-3020.
- ASTM D4251 – 89 (2016), Standard Test Method for Active Matter in Anionic Surfactants by Potentiometric Titration.https://www.astm.org/Standards/D4251.htm, assessed on 7 January 2019.
- Cihák, R. (2009). REACh – an overview. Interdisciplinary toxicology, 2: 42 – 44.
- Cocchi, M., Foca, G., Lucisano, M., Marchetti, A., Pagani, M. A., Tassi, L., &Ulrici, A. (2004). Classification of cereal flours by chemometric analysis of MIR spectra. Journal of Agricultural and Food Chemistry, 52: 1062 – 1067.
- Dir 92/69/EEC European Economic Community (O.J. L Official Journal of the European Communities No. L 383 A) A.10. Flammability (Solids). Annex V Testing Methods.
- Elraies, K.A.; Tan, I.; Awang, M.; Saaid, I. (2010). The synthesis and performance of sodium methyl ester sulfonate for enhanced oil recovery. Pet. Sci. Technol. 2010, 28, 1799 – 1806. http://dx.doi.org/10.1080/10916460903226072
- Ghazali, R. (2002). The effect of disalt on the biodegradability of methyl ester sulphonates (MES).Journal of Oil Palm Research, 14: 45 – 50.
- Ghazali, R., Awang, R., Cheong, K. W., Basri, M., Ismail, R., & Ahmad, S. (2004). Alkanolamides from 9, 10-dihyroxystearic acid.Journal of Oil Palm Research, 18: 231 – 238.
- Ghazali, R, Zolkarnain, N., Mohd Noor, M. A., Ishak, S. A., Musa, H., Abdullah, F., Shaari, A. L., &Roslan, N. A. (2019). MPOB’s Role in Sustaining Quality and Environmental Competitiveness of Malaysian OleochemicalIndustr.Palm Oil Developments, 71: 4 – 12.
- Global Market Insight (2020).Fatty methyl ester sulphonate market size, industry analysis report, regional outlook, application development potential, price trends, competitive market share & forecast, 2019-2025.https://www.gminsights.com/industry-analysis/fatty-methyl-estersulphonatemarket, accessed on 17 February 2020.
- Hesse, M., Meier, H., &Zeeh, B. (1997). Spectroscopic Methods in Organic Chemistry New York, George Thieme.https://doi.org/10.1002/pauz.19970260516, assessed on 2 September 2019.
- James A. Kent (2015). Soap, Fatty Acids, and Synthetic Detergents. Riegel’s Handbook of Industrial Chemistry, p 1098 – 1140.
- Jin, Y.; Tian, S.; Guo, J.; Ren, X.; Li, X.; Gao, S. (2016). Synthesis, characterization and exploratory application of anionic surfactant fatty acid methyl ester sulfonate from waste cooking oil. Journal Surfactants Detergent. 19, 467 – 475. http://dx.doi.org/10.1007/s11743-016-1813-z
- Khaled Abdalla, E., & Isa, M. T. (2012). The application of a new polymeric surfactant for chemical EOR.In: ROMERO-ZERÓN, L. (ed.) Introduction to Enhanced Oil Recovery (EOR) Processes and Bioremediation of Oil-Contaminated Sites. Intech Open, 45 – 70.
- Mat Dian, N. L. H., Sundram, K., &Idris, N. A. (2006).DSC study on the melting properties of palm oil, sunflower oil, and palm kernel olein blends before and after chemical interesterification.Journal of the American Oil Chemists’ Society, 83: 739 – 745.
- Md. Ali, A. R., &Dimick, P. S. (1994). Thermal Analysis of Palm Mid-Fraction, Cocoa Butter, and Milk Fat Blends by Differential Scanning Calorimetry, Journal of the American Oil Chemists’ Society, 71: 299 – 302.
- Maurad, Z. A., Ghazali, R., Siwayanan, P., Ismail, Z., &Ahmad, S. (2006). Alpha-sulfonated methyl ester as an active ingredient in palm-based powder detergents.Journal of Surfactants
and Detergents, 9: 161 – 167.
- Maurad, Z. A., Idris, Z., &Ghazali, R. (2017).Performance of palm-based methyl ester sulphonate (MES) in liquid detergent formulation.Journal of Oleo Science, 66: 677 – 687. DOI: 10.5650/jos.ess16190.
- Naseska, M. (2016).Fourier transform infrared spectroscopy. Department of Low and Medium Energy Physics-F2, Josef Stefan Institute, University of Ljubljana, Slovenia, 1 – 12.
- OECD TG 109 Guidelines for the Testing of Chemicals Method 109 Density of Liquids and Solids. Updated Guideline, adopted by the Council on 27th July 1995. p 1 – 5.
- OECD TG 102 Guideline for the Testing of Chemicals Method 102 Melting Point/Melting Range. Updated Guideline, adopted by the Council on 27th July 1995. p 1 – 8.
- Parveez, A. G. K., Hishamuddin, E., Loh, S. K., Meilina, O. A., Kamalrudin, M. S., Zainal, B. M. N., Aldrin, Z. A. H., Shamala, S., &Zainab, I. (2020). Oil Palm Economic Performance In Malaysia and R&D Progress in 2019. Journal of Oil Palm Research, 32(2), 159 – 190. https://doi.org/10.21894/jopr.2020.0032
- Permadani, R. L., Ibadurrohman, M., & Slamet (2018). Utilization of waste cooking oil as raw material for synthesis of methyl ester sulfonates (MES) surfactant. IOP Conference Series: Earth and Environmental Science, 105: 012036. . https://doi.org/10.1088/1755- 1315/105/1/012036.
- Registration, Evaluation, Authorisation and Restriction of Chemicals (REACh) (2006). 7. Information on the physicochemical properties of the substance. https://reachonline.eu/reach/en/annex-vii-7.html, assessed on 15 May 2019.
- Registration, Evaluation, Authorisation and Restriction of Chemicals (REACh) (2019). Physicochemical data requirements. http://www.prc.cnrs.fr/reach/en/physicochemical_data.html, accessed 5 August 2020.
- Salmiah, A., Zahariah, I., & Jasmin, S. (1998). Palm Based Sulphonated Methyl Esters and Soap. Journal of Oil Palm Research, 10(1), P 15 – 34.
- Satsuki, T., Umehara, K., & Yoneyama, Y. (1992). Performance and physicochemical properties of α-sulfo fatty acid methyl esters. Journal of the American Oil Chemists’ Society, 69: 672- 677. https://doi.org/10.1007/BF02635808.
- Silverstein, R. M. Bassler, G.C. (1962). Spectrometric identification of organic compounds. J. Chem. Educ. 39, 546. http://dx.doi.org/10.1021/ed039p546
- Smulders, E., Rybinski, W. V., Sung, E., Rähse, W., Steber, J., Wiebel, F. and Norskog, A. (2007). “Laundry Detergents” in Ullmann’s Encyclopedia of Industrial Chemistry. Wiley-VCH, Weinheim. DOI: 10.1002/14356007.a08_315.pub2
- Tolstorebrov, I., Eikevik, T. M., & Bantle, M. (2014). A DSC determination of phase transitions and liquid fraction in fish oils and mixtures of triacylglycerides.Food Research International, 58: 132 – 140.
- Vanderley José, P. João Paulo Arantes Rodrigues da, C., Tâmara Prado de, M., João Paulo Ribeiro de, O., & João Batista de, M. (2016). Physical-chemical properties of pesticides: concepts, applications, and interactions with the environment. Bioscience Journal, 32(3): 627 – 641.
- Weil, J.; Bistline, R.; Stirton, A. (1953). Sodium Salts of Alkyl Alpha-Sulfopalmitates and Stearates; Amer Chemical Soc 1155 16TH ST, NW 20036; Amer Chemical Soc: Washington, DC, USA, p. 4859 – 4860.
- Zulina A. M., Luqman C. A., Mohd S. A., Nor Nadiah A. K. S. & Zainab I. (2020). Preparation, Characterization, Morphological and Particle Properties of Crystallized Palm-Based Methyl Ester Sulphonates (MES) Powder. Molecules MDPI, 25, 2629; doi:10.3390/molecules25112629